New observations on high‐pressure phases in a shock melt vein in the Villalbeto de la Peña meteorite: Insights into the shock behavior of diopside

The petrology and mineralogy of shock melt veins in the L6 ordinary chondrite host of Villalbeto de la Peña, a highly shocked, L chondrite polymict breccia, have been investigated in detail using scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and electron probe microanalysis. Entrained olivine, enstatite, diopside, and plagioclase are transformed into ringwoodite, low‐Ca majorite, high‐Ca majorite, and an assemblage of jadeite‐lingunite, respectively, in several shock melt veins and pockets. We have focused on the shock behavior of diopside in a particularly large shock melt vein (10 mm long and up to 4 mm wide) in order to provide additional insights into its high‐pressure polymorphic phase transformation mechanisms. We report the first evidence of diopside undergoing shock‐induced melting, and the occurrence of natural Ca‐majorite formed by solid‐state transformation from diopside. Magnesiowüstite has also been found as veins injected into diopside in the form of nanocrystalline grains that crystallized from a melt and also occurs interstitially between majorite‐pyrope grains in the melt‐vein matrix. In addition, we have observed compositional zoning in majorite‐pyrope grains in the matrix of the shock‐melt vein, which has not been described previously in any shocked meteorite. Collectively, all these different lines of evidence are suggestive of a major shock event with high cooling rates. The minimum peak shock conditions are difficult to constrain, because of the uncertainties in applying experimentally determined high‐pressure phase equilibria to complex natural systems. However, our results suggest that conditions between 16 and 28 GPa and 2000–2200 °C were reached.     

From back-analysis to run-out prediction: a case study in the Western Italian Alps

Rock avalanches are complex phenomena that occur with a low frequency but which have a high destructive potential. As a consequence, the people who are responsible for the management of a territory are more and more interested in predicting the possible evolutions of well-known potential events. Tackling the above problems from a quantitative point of view, the RASH3D code, based on continuum mechanics concepts, has been here used to predict the evolution of a potential rock avalanche in the Western Italian Alps. A calibration-based approach, in which rheological parameters are constrained by systematic adjustment during trial-and-error back-analysis of past events similar to the landslide under investigation, is proposed to set rheological parameter values to be used for prediction purposes. The back-analysis of a 2?10⁶ m³ rock avalanche located in the Divedro Valley, close to the area of the potential event, has then been analysed using both a frictional and a Voellmy rheology. The characteristics of the slope and the dynamics of the event have made the frictional rheology more suitable to come to the correct simulation of the historical case. The back-analysis results have contributed not only in the selection of the rheological parameter values but also in the choice of the type of rheological law to use in the carried out forward-analyses.     

Curie Point Depth Estimates and Correlation with Subduction in Mexico

We investigate the regional thermal structure of the crust in Mexico using Curie Point Depth (CPD) estimates. The top and bottom of the magnetized crust were calculated using the power-density spectra of the total magnetic field from the freely available ??Magnetic Anomaly Map of North America??. We applied this method to estimate the regional crustal thermal structure in overlapping square windows of 2°?×?2°. The CPD estimates range between 10 and 40?km and show several regions of relatively shallow and deep magnetic sources, with a general inverse correlation with measured heat flow. A deep CPD region (20?C30?km) is located in the fore-arc area where the subducting Cocos plate has a flat-slab geometry. This deep region is bound to the NW and SE by shallow CPD areas beneath the states of Michoacan (CPD?=?12?C16?km) and Oaxaca (CPD?=?~16?km), respectively. There is a good spatial correlation between this deep CPD area and two main fracture zones located on the incoming Cocos plate (Orozco and O??Gorman fracture zones), suggesting that subduction plays an important role in setting apart different CPD provinces along the Mexican coast. Another deep CPD (16?C32?km) area corresponds to the region where the Rivera plate subducts beneath Jalisco block. The Trans-Mexican Volcanic Belt is characterized by a decrease in Curie depths from west (16?C20?km) to east (10?C12?km). Finally, several deep CPD areas are situated in the back-arc region where old Mesozoic terrains are present. Our results suggest that the main control on the crust??s regional thermal structure in the fore-arc and volcanic arc regions is due to the subduction of the Cocos and Rivera plates beneath Mexico.     

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.     

Response of suspended sediment particle size distributions to changes in water chemistry at an Andean mountain stream confluence receiving arsenic rich acid drainage

Acid drainage is an important water quality issue in Andean watersheds, affecting the sustainability of urban, agricultural, and industrial activities. Mixing zones receiving acid drainage are critical sites where changes in pH and chemical environment promote the formation and dissolution of iron and aluminum oxy/hydroxides. These particles can significantly change the speciation of toxic metals and metalloids throughout drainage networks via sorption, desorption, and settling processes. However, little is known about the behavior of particle size distributions (PSDs) in streams affected by acid drainage and their relationship to metal speciation. This work studied: (a) the PSDs for a wide range of mixing ratios found at a fluvial confluence affected by acid drainage, and (b) the response of PSDs and arsenic speciation to environmental changes found when the particles approach complete mixing conditions. The confluence between the Azufre River (pH ~ 2, high concentration of dissolved metals) and Caracarani River (pH = 8.6, low concentration of dissolved metals) was used as a representative model for study. Field measurements show a bimodal PSD with modal diameters of ~50 and 300 μm. At shorter distances from the junction, the smaller modes with smaller particle volumes were dominant across the stream cross‐sections. A systematic shift towards larger particle sizes and larger particle volumes occurred downstream. The analysis of laboratory PSDs for Azufre/Caracarani mixing ratios between 0.01 and 0.5 (pH from 6.2 to 2.3) showed a bimodal trend with ~15 and 50 μm characteristic diameters; larger particles formed at pH>4. When particle suspensions were transferred in laboratory experiments from very low pH to full mixing conditions (pH ~ 2.8 and mixing ratio ~ 0.25) particle sizes varied, and the dissolved arsenic concentration decreased. The observed reaction kinetics were slow compared to the time scale of advective transport, creating opportunities for engineered controls for arsenic. This work contributes to a better understanding of the chemical‐hydrodynamic interactions in watersheds affected by mining, and identifying opportunities to improve water quality at points of use.     

Observations of a Radio-Quiet Solar Preflare

The preflare phase of the flare SOL2011-08-09T03:52 is unique in its long duration, in that it was covered by the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) and the Nobeyama Radioheliograph, and because it showed three well-developed soft X-ray (SXR) peaks. No hard X-rays (HXR) are observed in the preflare phase. Here we report that no associated radio emission at 17 GHz was found either, despite the higher sensitivity of the radio instrument. The ratio between the SXR peaks and the upper limit of the radio peaks is higher by more than one order of magnitude than the ratio in regular flares. The result suggests that the ratio between acceleration and heating in the preflare phase was different than in regular flares. Acceleration to relativistic energies, if any, occurred with lower efficiency.     

Snow carrots after the Chelyabinsk event and model implications for highly porous solar system objects

After the catastrophic disruption of the Chelyabinsk meteoroid, small fragments formed funnels in the snow layer covering the ground. We constrain the pre‐impact characteristics of the fragments by simulating their atmospheric descent with the atmospheric entry model. Fragments resulting from catastrophic breakup may lose about 90% of their initial mass due to ablation and reach the snow vertically with a free‐fall velocity in the range of 30–90 m s^?1. The fall time of the fragments is much longer than their cooling time, and, as a consequence, fragments have the same temperature as the lower atmosphere, i.e., of about ?20 °C. Then, we use the shock physics code iSALE to model the penetration of fragments into fluffy snow, the formation of a funnel and a zone of denser snow lining its walls. We examine the influence of several material parameters of snow and present our best‐fit model by comparing funnel depth and funnel wall characteristics with observations. In addition, we suggest a viscous flow approximation to estimate funnel depth dependence on the meteorite mass. We discuss temperature gradient metamorphism as a possible mechanism which allows to fill the funnels with denser snow and to form the observed “snow carrots.” This natural experiment also helps us to calibrate the iSALE code for simulating impacts into highly porous matter in the solar system including tracks in the aerogel catchers of the Stardust mission and possible impact craters on the 67P/Churyumov‐Gerasimenko comet observed recently by the Rosetta mission.     

Influence of nutritional stress on digestive enzyme activities in juveniles of two marine clam species, Ruditapes decussatus and Venerupis pullastra

The potential use of digestive activities as indicators of the nutritional status in bivalves is discussed in relation to the results obtained in two clam species exposed to starvation and refeeding. Activities of some digestive enzymes (amylase, laminarinase, cellulase, and protease) were measured in juveniles of two commercially interesting species of clams, Ruditapes decussatus and Venerupis pullastra. The specimens were fed normally, being after subjected to a 15-days starvation and a further refeeding period. Samples were obtained at different moments of such feeding schedule to evaluate enzymes as well as weight (live, dry and organic) and length, in order to calculate growth rates and feeding efficiencies. Starvation led to a major decrease in clam growth as measured by dry weight and a negative growth as measured by organic weight, this coinciding with a certain degree of growth of the shell and a consumption of soft tissue. This response occurred more rapidly in R. decussatus but was of a lower magnitude than in V. pullastra. Activity of carbohydrases decreased rapidly in both species with starvation, although protease activity was maintained in R. decussatus. Recovery after the end of starvation was not similar in both species; while R. decussatus attained similar growth rates and enzyme activities to those measured prior to nutritional stress, V. pullastra only recovered 50% of its initial values. For both species of bivalves it can be concluded that digestive enzymes, and more specifically amylase, could be used as indicative of their nutritional condition.